| |
TOFc
|
Productivityd
|
STYe
|
|---|
|
Xb
|
0.2
|
0.7
|
0.2
|
0.7
|
0.2
|
0.7
|
|
McGlc
|
2.1 (6.1)
|
0.14 (0.6)
|
174 (353)
|
11 (32)
|
50 (101)
|
3.2 (9)
|
|
PcGlc
|
1.2 (3.6)
|
0.51 (1.9)
|
135 (284)
|
57 (149)
|
29 (61)
|
12 (32)
|
- aUsing an S/E ratio of 55′000 mol mol–1; 35 °C; initial concentration of 2: 300 mM. The quantification of quercetin and compound 6 enabled the determination of the total (i.e., hydrolysis and transglycosylation) and the transglycosylation-specific conversion, respectively. The data in parentheses were calculated based on quercetin as the reaction product
- bX: conversion of glycosyl donor 2
- cTurnover frequency: 104 mol of 6 or quercetin·(mole of catalyst·h)–1
- dCatalyst productivity: g of 6 or quercetin·(g catalyst·h)–1
- eSpace–time yield: g of 6 or quercetin·(L·h)–1
