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Table 3 13C-NMR chemical shifts of hydrolysis products of G-Rc by BG-1

From: Purification and characterization of a novel ginsenoside Rc-hydrolyzing β-glucosidase from Armillaria mellea mycelia

Carbon no G-Rd C-Mc1 G-F2 C-Mc C-K
Aglycone moiety
 1 39.0 39.6 38.9 39.9 39.8
 2 26.6 27.2 26.5 26.6 26.6
 3 88.8 89.2 88.6 78.5 78.7
 4 39.5 40.1 39.5 39.8 39.9
 5 56.2 56.8 56.1 56.6 56.8
 6 18.3 18.2 18.2 18.3 19.2
 7 35.0 35.5 34.9 35.6 35.6
 8 39.9 40.4 39.8 40.0 40.0
 9 50.0 50.6 50.0 50.7 50.8
 10 36.7 37.3 36.7 37.8 37.8
 11 30.6 30.6 30.6 30.6 31.3
 12 70.1 70.6 70.1 70.6 70.6
 13 49.3 49.8 49.5 49.9 50.0
 14 51.4 52.0 51.2 51.8 52.0
 15 30.7 30.4 29.8 31.1 31.4
 16 26.5 27.0 26.4 26.2 26.3
 17 51.5 51.8 51.5 52.1 51.9
 18 16.1 16.7 16.1 16.7 16.5
 19 15.8 16.4 15.7 16.5 16.8
 20 83.2 82.8 83.1 83.8 83.8
 21 22.3 22.3 22.3 22.8 22.8
 22 35.9 36.5 35.8 36.6 36.7
 23 23.1 23.6 23.1 23.6 23.7
 24 125.8 126.4 125.7 125.3 126.5
 25 130.8 131.3 130.8 131.4 131.4
 26 25.7 26.2 25.6 26.2 26.2
 27 17.6 17.2 17.6 17.8 17.9
 28 27.9 28.5 27.9 27.2 28.8
 29 16.5 16.7 16.6 16.8 16.7
 30 17.2 17.8 17.1 17.8 17.6
3-Glucopyranosyl (inner)
 1′ 105.0 105.4 106.7   
 2′ 83.2 76.2 75.6   
 3′ 78.1 79.3 77.8   
 4′ 71.5 72.3 71.7   
 5′ 78.1 79.1 78.2   
 6′ 62.6 63.0 62.8   
3-Glucopyranosyl (outer)
 1″ 105.9     
 2″ 77.0     
 3″ 79.1     
 4″ 71.5     
 5″ 78.1     
 6″ 62.7     
20-Glucopyranosyl
 1′ 98.1 98.5 98.1 98.5 98.7
 2′ 75.0 75.2 75.0 75.4 75.6
 3′ 77.8 78.6 79.0 79.7 77.8
 4′ 71.4 72.1 71.3 72.6 72.1
 5′ 78.0 76.9 78.5 77.0 78.5
 6′ 62.5 68.8 62.5 68.9 63.4
20-Arabinofuranosyl
 1″   110.5   110.5  
 2″   83.7   83.7  
 3″   78.7   78.6  
 4″   86.5   86.5  
 5″   63.0   83.1