Table 1 Main metabolites of extract form spores and mycelia of Cordyceps fumosorosea

1.66 (1)

[M−H]⁻181.0729, 1.1

200

C₆H₁₄O₆

Mannitol^a

4.83 (2)

[M−H]⁻ 243.0625, 0.2; [2 M−H]⁻ 487.1321, 0.3

[M + H]⁺ 245.0763, 0.5; [M-C₅H₇O₄]⁺113.0349, 0.3

206, 261

C₉H₁₂N₂O₆

Uridine^a

9.74 (3)

[M-H]⁻ 266.0899, 0.4; [M-C₅H₉O₄]⁻ 134.0476, 0.4

[M + H]⁺ 268.1045, 0.5; [M-C₅H₇O₄]⁺136.0822, 0.6

205, 258

C₁₀H₁₃N₅O₄

Adenine^a

14.13 (4)

[M−H]⁻ 310.1155, 0.2; [M-C₅H₉O₄]⁻ 178.0731, 0.3

[M + H]⁺ 312.1305, 0.3; [M-C₅H₇O₄]⁺180.0876, 0.4

209, 265

C₁₂H₁₇N₅O₅

N⁶-(2-Hydroxyethyl)-Adenosine^a

16.41 (5)

[M−H]⁻ 352.1266, 0.3; [M-C₅H₉O₄]⁻ 220.0839, 0.1

[M + H]⁺ 354.1410, 0.2; [M-C₅H₇O₄]⁺ 222.0979, 0.7

209, 265

C₁₄H₁₉N₅O₆

Unknown

22.24 (6)

[M−H]⁻ 491.1565, 0.6; [M + H]⁺ 493.1699, 0.5

262, 361

C₂₄H₂₈O₁₁

Unknown

22.43 (7)

[M−H]⁻ 507.1513, 0.5; [M + H]⁺ 509.1658, 0.4

262, 361

C₂₄H₂₈O₁₂

Unknown

28.85 (8)

[M−H]⁻ 297.1718, 1.1;

[M + H]⁺ 299.1859, 0.6; [M + Na]⁺ 321.1680, 0.8

200

C₁₆H₂₆O₅

Ovalicin-4α-alcohol

32.41 (9)

32.88 (10)

[M−H]⁻ 476.2785, 0.2;

[M + H]⁺ 478.2928, 0; [M + Na]⁺ 500.2744, 0.4

200

C₂₃H₄₄NO₇P

Unknown

34.28 (11)

34.83 (12)

[M + COOH]⁻ 542.3695, 0.3;

[M + H]⁺ 498.3791, 0.2; [M-C₁₈H₂₉O]⁺ 236.1495, 0.3

200

C₂₈H₅₁NO₆

Unknown

35.94 (13)

[M−H]⁻ 486.2863, 0.5; [M + H]⁺ 488.3010, 0.7

215

C₂₇H₄₁N₃O₅

Beauveriolide I^b

38.36 (14)

[M−H]⁻ 734.4031, 0.9; [M + H]⁺ 736.4173, 0.5; [M + NH₄]⁺ 753.4438, 0.5; [M + Na]⁺ 758.3985, 0.2

210

C₄₁H₅₇N₃O₉

Beauveriolide E

39.06 (15)

[M-H]⁻ 782.4039, 0.7; [M + H]⁺ 784.4171, 0.3; [M + NH₄]⁺ 801.4439, 0.6; [M + Na]⁺ 806.3991, 0.4

255

C₄₅H₅₇N₃O₉

Beauvericin^b

39.45 (16)

[M-H]⁻ 804.3469, 0.8; [M + H]⁺ 806.3612, 0.5

225, 280

C₄₁H₅₁N₅O₁₂

Conoideocrellide D

39.92 (17)

[M−H]⁻ 796.4185, 0.6; [M + H]⁺ 798.4331, 0.7; [M + NH₄]⁺ 815.465, 0.6; [M + Na]⁺ 820.4138, 0.8

260

C₄₆H₅₉N₃O₉

Beauvericin A^a

41.69 (18)

[M−H]⁻ 279.2332, 0.2; [M + H]⁺ 281.2469, 0.6

200

C₁₈H₃₂O₂

Linoleic acid

43.21 (19)

[M−H]⁻ 255.2334, 0.4; [M + H]⁺ 257.2473, 0.2

200

C₁₆H₃₂O₂

Palmitic acid

43.54 (20)

[M−H]⁻ 281.2481, 0.5; [M + H]⁺ 283.2629, 0.3

200

C₁₈H₃₄O₂

Oleic acid