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Table 1 Sulfides conversion catalyzed by BVMOAf1 Af1

From: Cloning, overexpression and biocatalytic exploration of a novel Baeyer-Villiger monooxygenase from Aspergillus fumigatus Af293

Substrate

Time (min)a

Sulfoxide (%)

Sulfone (%)

ee (%)

180

88

8

>99 (S)

60

56

37

>99 (S)

180

25

75

>99 (S)

  1. a Reactions were monitored by sampling at regular time intervals. Full substrate conversion was observed at 180 min in both cases. For GC conditions, see online resource.